LBO, namely Lithium Triborate Crystal (LiB₃O₅), is an excellent nonlinear optical crystal. It features a wide transmission range, high damage threshold, moderate nonlinear coefficient, and excellent optical uniformity, and is widely used in various laser frequency conversion applications.
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Physical Quantity
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Value
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Remarks
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Crystal Structure
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Orthorhombic
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Lattice Parameters
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a=8.4473 Å, b=7.3788 Å, c=5.139 Å, Z=2, Room temperature
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Room temperature
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Melting Point
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834 °C
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Mohs Hardness
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6
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Density
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2.47 g/cm³
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Thermal Conductivity
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3.5 W/m·K
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Room temperature
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Thermal Expansion Coefficients
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αₓ=10.8×10⁻⁶/K, αᵧ=−8.8×10⁻⁶/K, α_z=3.4×10⁻⁶/K, 25–200 °C
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25–200 °C range
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Transparency Range
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160–2600 nm
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SHG Phase Matching Range
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Type I: 551–2600 nm; Type II: 790–2150 nm
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Room temperature
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Thermo‑optic Coefficients
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dnₓ/dT=−9.3×10⁻⁶/°C, dnᵧ/dT=−13.6×10⁻⁶/°C, dnz/dT=(−6.3−2.1λ)×10⁻⁶/°C
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Room temperature
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Absorption Coefficient
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<0.1%/cm @1064 nm; <0.3%/cm @532 nm
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Beam Divergence (Angular Acceptance)
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6.54 mrad·cm (Φ, Type I, 1064 nm SHG); 15.27 mrad·cm (θ, Type II, 1064 nm SHG)
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Temperature Bandwidth
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4.7 °C·cm (Type I, 1064 nm SHG); 7.5 °C·cm (Type II, 1064 nm SHG)
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Angular Acceptance
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6.54 mrad·cm (Φ, Type I, 1064 nm SHG); 15.27 mrad·cm (θ, Type II, 1064 nm SHG)
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Nonlinear Optical Coefficients
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d₃₁=1.05±0.09 pm/V; d₃₂=−0.98±0.09 pm/V; d₃₃=0.05±0.006 pm/V
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Sellmeier Equations (λ in μm)
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nx²=2.454140+0.011249/(λ²−0.011350)−0.014591λ²−6.60×10⁻⁵λ⁴; ny²=2.539070+0.012711/(λ²−0.012523)−0.018540λ²+2.00×10⁻⁴λ⁴; nz²=2.586179+0.013099/(λ²−0.011893)−0.017968λ²−2.26×10⁻⁴λ⁴
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Item
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Specific Parameter
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Dimensional Tolerance
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(W±0.1mm)×(H±0.1mm)×(L+0.5/-0.1mm), custom sizes accepted
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Clear Aperture
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95% of central region diameter
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Flatness
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λ/8 @ 633 nm
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Transmitted Wavefront Distortion
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λ/8 @ 633 nm
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Surface Finish
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10/5 per MIL-PRF-13830B standard
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Parallelism
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20 arcsec
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Perpendicularity
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15 arcmin
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Angular Deviation
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Δθ ≤ 0.1°, Δφ ≤ 0.1°
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Chamfer
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≤ 0.2 mm × 45°
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Edge Chipping
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≤ 0.1 mm
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Damage Threshold
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>10 GW/cm² @ 1064 nm, 10 ns, 10 Hz (polished wafer); >0.5 GW/cm² @ 532 nm, 10 ns, 10 Hz (AR-coated)
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Quality Guarantee Period
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1 year under normal use
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| LBO Crystal Transmittance Curve | LBO Nonlinear Crystal SHG |
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| Type I LBO OPO Tuning Curve | Type II LBO OPO Tuning Curve |