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CLBO

CLBO, namely Cesium Lithium Borate Crystal (CsLiB₆O₁₀), is a new type of nonlinear optical crystal with excellent properties. It features a wide transmission range, high nonlinear coefficient, large spectral and temperature bandwidths, and no second harmonic absorption. It performs outstandingly in the fields of high-power laser frequency conversion and deep ultraviolet laser generation.

Technical Specifications
Custom specifications available upon request

Product Features

Our company can provide high-quality, large-size CLBO crystals. By precisely controlling the crystal growth environment and process parameters, we effectively suppress the effects of hygroscopicity, reduce internal inclusions and stress defects within the crystal, and significantly improve the crystal's optical uniformity and laser damage threshold. It is suitable for applications such as high-power Nd:YAG laser fourth-harmonic and fifth-harmonic generation, as well as deep ultraviolet laser-related optical parametric conversion.
 

Basic Characteristics

Physical Quantity
Value
Remarks
Crystal Structure
Tetragonal system
/
Lattice Parameters
a=b=10.494 Å, c=8.939 Å (1 Å=10⁻¹⁰ m), Room temperature
Room temperature
Symmetry
Z=4
Melting Point
Approx. 844.5 °C
/
Mohs Hardness
5.5
/
Density
2.461 g/cm³
Room temperature
Thermal Conductivity
1.25 W/m·K
Room temperature
Transmission Range
175 nm–2750 nm
/
Damage Threshold
26 GW/cm²
Thermo-optic Coefficients
dno/dT=-1.9×10⁻⁶/°C, dne/dT=-0.5×10⁻⁶/°C, Room temperature
Room temperature
Absorption Coefficient
266 nm UV:<0.05 cm⁻¹; 532–1064 nm Visible-NIR:<0.01 cm⁻¹
/
Refractive Index
1064nm: ne=1.4340, no=1.4838; 532nm: ne=1.4445, no=1.4971
Walk-off Angle
1.78°@1064nm, 1.83°@532nm, 0.98°@488nm
/
Angular Acceptance
0.5–1 mrad·cm (e.g. 266nm 4th harmonic)
/
Nonlinear Optical Coefficient
deff(I)=d₃₆ sinθₘ sin(2φ); deff(II)=d₃₆ sin(2θₘ) sin(2φ)
Sellmeier Equations
nₒ²=2.2104+0.01018/(λ²–0.01424)–0.01258λ²; nₑ²=2.0588+0.00838/(λ²–0.01363)–0.00607λ², 25°C
25°C
 

LBO Crystal Specification Parameters

Item
Specific Parameter
Dimensional Tolerance
(W±0.1mm)×(H±0.1mm)×(L+0.5/-0.1mm), custom sizes accepted
Clear Aperture
95% of central region diameter
Flatness
λ/6 @ 633 nm
Transmitted Wavefront Distortion
λ/8 @ 633 nm
Surface Finish
10/5 per MIL-PRF-13830B standard
Parallelism
20 arcsec
Perpendicularity
15 arcmin
Angular Deviation
Δθ ≤ 0.1°, Δφ ≤ 0.1°
Chamfer
≤ 0.2 mm × 45°
Edge Chipping
≤ 0.1 mm
Quality Guarantee Period
1 year under normal use
 

CLBO Curve Graphs 

CLBO Transmittance Spectrum

Phase-Matching Angles of Type I and Type II vs. Fundamental Wavelength

 

 

Application Fields:

1. Semiconductor Industry.​

CLBO crystals can achieve harmonic outputs at 193 nm and 266 nm, with a cutoff wavelength as low as 180 nm, making them ideal for semiconductor lithography and semiconductor inspection. In semiconductor lithography, the UV laser generated by CLBO enables fine patterning of chips, improving integration density and performance.

2. Materials Processing.​

With high damage threshold and low absorption, and no two‑photon absorption, CLBO crystals are suitable for high‑power laser systems. Lasers derived from CLBO allow precise cutting, etching, or modification without damaging surrounding material—essential precision for industries such as electronics, e.g., processing tiny electronic components.

3. Bomedical Field.​

The excellent efficiency of CLBO‑generated UV lasers makes them valuable in medical diagnostics. UV light penetrates tissue more deeply and provides higher clarity, delivering clearer and more detailed images for more accurate and timely diagnosis, such as detecting small tumors or vascular abnormalities.

4. UV Lidar Applications.​

Thanks to its properties, CLBO is suitable for UV lidar systems used in target detection and environmental monitoring. The UV laser produced by CLBO enables more precise detection and identification.

 

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